Over 11% Efficient CuGaSe2 Solar Cells Without Using KCN Treatment.

Autor: Gong, Junbo, Gao, Duoqi, Ma, Zengyang, Yang, Xuke, Zhang, Junjun, Liu, Xinxing, Chen, Chao, Tang, Jiang, Da, Bo, Li, Jianmin, Fang, Guojia, Xiao, Xudong
Předmět:
Zdroj: Solar RRL; Dec2022, Vol. 6 Issue 12, p1-9, 9p
Abstrakt: CuGaSe2 (CGS) has a bandgap energy of 1.68 eV and is theoretically very suitable to be in tandem with silicon or Cu(In,Ga)Se2 solar cells. However, due to the high quantity of surface defects, high‐performance CGS usually relies on a KCN surface treatment, which is a high‐toxic process and restricts its further development. Herein, by reducing the exposure time to air of the CGS layer as far as possible and developing a new absorber growth procedure to reduce the surface CuxSe generation, grain size is successfully increased and interface recombination is reduced without the use of KCN. Combined with a simple annealing process, the defect concentration is successfully decreased and the depletion width is broadened dramatically and the power conversion efficiency is promoted to 11.05% without any traditionally used KCN treatment. This work provides a nontoxic and low‐pollution way to fabricate high‐efficient CGS solar cells. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index