Thiolated Janus Silsesquioxane Tetrapod: New Precursors for Functional Materials.

Autor:	Laird, Mathilde, Carcel, Carole, Unno, Masafumi, Bartlett, John R., Wong Chi Man, Michel
Předmět:	MASS spectrometry FUNCTIONAL groups MOIETIES (Chemistry) TETRAPODS POLYMERIZATION OLIGOMERS
Zdroj:	Molecules; Nov2022, Vol. 27 Issue 22, p7680, 14p
Abstrakt:	Herein, we report synthetic strategies for the development of a bifunctional Janus T4 tetrapod (Janus ring), in which the orthogonal silsesquioxane and organic faces are independently functionalized. An all-cis T4 tetrasilanolate was functionalized to introduce thiol moieties on the silsesquioxane face and naphthyl groups on the organic face to introduce luminescent and self-organization properties. The stepwise synthesis conditions required to prepare such perfectly defined oligomers via a suite of well-defined intermediates and to avoid polymerization or reactions over all eight positions of the tetrapod are explored via 29Si, 13C and 1H NMR, FTIR and TOF-ESI mass spectroscopy. To the best of our knowledge, this is one of the few reports of Janus T4 tetrapods, with different functional groups located on both faces of the molecule, thus expanding the potential range of applications for these versatile precursors. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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