Reducing Optical Reflection Loss for Perovskite Solar Cells Via Printable Mesoporous SiO2 Antireflection Coatings.

Autor: Wang, Xiadong, Wang, Wei, Liu, Jiale, Qi, Jianhang, He, Yue, Wang, Yifan, Hu, Wenjing, Cheng, Yanjie, Chen, Kai, Hu, Yue, Mei, Anyi, Han, Hongwei
Předmět:
Zdroj: Advanced Functional Materials; 10/26/2022, Vol. 32 Issue 44, p1-9, 9p
Abstrakt: The power conversion efficiency (PCE) of single‐junction perovskite solar cells (PSCs) is being rapidly promoted towards their theoretical limit, with a certified value of 25.7%. Reducing optical loss will further contribute to PCE improvement. Here, the optical loss including reflection loss, absorption loss, and transmission loss in printable mesoscopic perovskite solar cells (p‐MPSCs) is analyzed. A printable mesoporous SiO2 antireflection coating for improving the transmittance of the fluorine‐doped tin oxide (FTO) glass substrate by reducing optical reflection at the air/glass interface is reported. With modulated porosity and thickness, the mesoporous SiO2 film constructs a graded refractive index interface and increases the transmittance of FTO glass by ≈2%–4% in the spectral range of 350–800 nm at normal incident angle with the highest transmittance improved from 85% to 89%. The SiO2 coating also exhibits wide‐angle and broadband antireflection properties. The coatings successfully help p‐MPSCs obtain about an average 3% enhancement in the short‐circuit current density (JSC) and PCE. This study demonstrates the necessity of optical management for efficient solar cells and provides a cost‐effective and scalable antireflection coating for the future realistic application of PSCs. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index