Separation of Metalloporphyrins by TLC.

Autor: Podgórna, Marzena
Zdroj: Journal of Planar Chromatography - Modern TLC; Dec2001, Vol. 14 Issue 6, p449-453, 5p
Abstrakt: Summary: Complexes of hydroxy- and alkyloxytetraphenylporphyrins with Cu (II), Zn (II), and Ni (II) have been prepared and their chromatographic behavior in adsorption and partition thin-layer chromatography has been investigated. Gutman topological indexes, Mν, and the screening effect, SE, of the hydrocarbon chains on the electron pairs of the oxygen atoms of–OR groups have been calculated for the metalloporphyrin derivatives studied. The correlation between these and chromatographic retention, expressed as RM values, has been studied. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index