Ni-catalyzed C–S bond construction and cleavage.

Autor: Huang, Su, Wang, Ming, Jiang, Xuefeng
Předmět:
Zdroj: Chemical Society Reviews; 10/7/2022, Vol. 51 Issue 19, p8351-8377, 27p
Abstrakt: Sulfur-containing compounds have attracted considerable interest due to their wide-ranging applications in pharmaceuticals, agriculture, natural products, and organic materials. The development of efficient and rapid methods for the construction and transformation of sulfur-containing compounds is of great importance. Since nickel is inexpensive and has a variety of valence states, strong nucleophilicity and low energy barriers for oxidative addition, the construction and transformation of sulfur-containing compounds by nickel-catalyzed cross-coupling have become important strategies. In addition, sulfur-containing compounds have also been playing increasingly important roles in the field of cross-coupling due to their thermodynamically stable but dynamic activity. This review will focus on nickel-catalyzed construction and transformation of various sulfide-containing compounds, such as sulfides, disulfides, and hypervalent sulfur-containing compounds. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index