Synthesis and Investigation of Physical and Chemical Properties of Nanopowders and Ceramics in the La2O3–SrO–Ni(Co,Fe)2O3 System.

Autor: Kalinina, M. V., Dyuskina, D. A., Khamova, T. V., Efimova, L. N., Shilova, O. A.
Zdroj: Inorganic Materials: Applied Research; Oct2022, Vol. 13 Issue 5, p1408-1413, 6p
Abstrakt: By the joint crystallization of solutions of nitrate salts, fine powders of La1 – xSrxNiO3, La1 ‒xSrx-CoO3, and La1 –xSrxFe0.7Ni0.3O3 (x = 0.30 and 0.40) are synthesized. They have a specific pore volume of 0.018–0.035 cm3/g and a specific surface area of 15–31 m2/g. On their basis, ceramic nanomaterials of a given composition with CSR ~ 64–70 nm (1300°С) are obtained. The physicochemical properties of the obtained ceramic are studied; it is revealed that the ceramic is a solid solution with open porosity in a range of 17–30% and a high value of the relative density of 94%. In terms of their physicochemical properties (open porosity, density, coefficient of thermal expansion), the obtained ceramic materials are promising as solid oxide cathodes for intermediate-temperature fuel cells. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index