Synthetic Studies toward Australifungin.

Autor: Kim, Jinwoo
Zdroj: Synlett; Oct2022, Vol. 33 Issue 16, p1625-1628, 4p
Abstrakt: As a fungal metabolite, australifungin possesses an α-diketone and a β-ketoaldehyde moiety on its trans -decalin backbone. Microwave-assisted intramolecular Diels–Alder reaction was used as a key strategy to establish the trans -decalin moiety. Further functionalization of the ring B side chain installed the β-ketoaldehyde, one of the two unique functional groups along with the α-diketone. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index