Late-stage derivatization of a (B,O)2-doped perylene.

Autor: Ouadoudi, Omar, Kaehler, Tanja, Çevik, Enes Görkem, Bolte, Michael, Stöger, Berthold, Virovets, Alexander, Lerner, Hans-Wolfram, Wagner, Matthias
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 9/21/2022, Vol. 51 Issue 35, p13195-13198, 4p
Abstrakt: Regioselective di- and tetrabrominations of the (B,O)2-perylene 1 afford derivatives 2–4. Despite their poor solubility, 2 and 4 could be used in Stille-type coupling reactions to introduce two C≡CMe (5) or four C≡C(p-C6H4tBu) substituents (6), respectively. The alkynylated derivatives show blue-green photoluminescence with appreciable quantum efficiencies. [ABSTRACT FROM AUTHOR]
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