IL-Functionalized Mg 3 Al-LDH as New Efficient Adsorbent for Pd Recovery from Aqueous Solutions.

Autor:	Cocheci, Laura, Lupa, Lavinia, Tolea, Nick Samuel, Lazău, Radu, Pode, Rodica
Předmět:	PLATINUM group AQUEOUS solutions PRECIOUS metals PALLADIUM SOLID phase extraction IONIC liquids ADSORPTION capacity SELF-propagating high-temperature synthesis
Zdroj:	International Journal of Molecular Sciences; Aug2022, Vol. 23 Issue 16, p9107-N.PAG, 22p
Abstrakt:	Palladium is a noble metal of the platinum group metals (PGMs) with a high value and major industrial applications. Due to the scarce palladium resources, researchers' attention is currently focused on Pd ions recovery from secondary sources. Regarding the recovery process from aqueous solutions, many methods were studied, amongst which adsorption process gained a special attention due to its clear advantages. Moreover, the efficiency and the selectivity of an adsorbent material can be further improved by functionalization of various solid supports. In this context, the present work aims at the synthesis and characterization of Mg3Al-LDH and its functionalization with ionic liquid (IL) (Methyltrialkylammonium chloride) to obtain adsorbent materials with high efficiency in Pd removal from aqueous solutions. The maximum adsorption capacity developed by Mg3Al-LDH is 142.9 mg Pd., and depending on the functionalization method used (sonication and co-synthesis, respectively) the maximum adsorption capacity increases considerably, qmax-Mg3Al IL-US = 227.3 mg/g and qmax-Mg3Al IL-COS = 277.8 mg/g. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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