Crystal structure of poly[μ2-aqua-aqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2N:N′)-(μ2-4,4′-(1H-1,2,4-triazole-3,5-diyl)dibenzoato-κ2O:O′)-(μ4-4,4′-(1H-1,2,4-triazole-3,5-diyl)dibenzoato-κ5O,O′:O″:O′″:O′″)dicobalt(II)] – water – dimethylformamide (1/1/1) C44H43N11O12Co2

Autor: Wang, Qin, Gao, Jia-Hao, Zhang, Sheng-Rui, Gao, Yan-Hong, Lu, Jiu-Fu
Předmět:
Zdroj: Zeitschrift für Kristallographie / New Crystal Structures; Oct2022, Vol. 237 Issue 5, p869-872, 4p
Abstrakt: Keywords: 2168454 EN 2168454 869 872 4 08/25/22 20221001 NES 221001 Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters. Meanwhile, Co2 exhibits another distorted octahedral geometry with one nitrogen atom (N10) of 1,3-di(1 I H i -imidazol-1-yl)propane, one oxygen atom (O9) of bridging coordinated water molecule, one oxygen atom (O10) of one unidentate water, three atoms (O6,O7,O8) of three 4,4'-(1 I H i -1,2,4-triazole-3,5-diyl)dibenzoate ligands. The six atoms that coordinate with Co1 come from one nitrogen atom (N7) of 1,3-di(1 I H i -imidazol-1-yl)propane, one oxygen atom (O9) of bridged water, three unidentate coordinated oxygen atoms (O1,O3,O5) of three 4,4'-(1 I H i -1,2,4-triazole-3,5-diyl)dibenzoate ligands, one bridged carboxyl oxygen atom (O8) of one 4,4'-(1 I H i -1,2,4-triazole-3,5-diyl)dibenzoate ligand. [Extracted from the article]
Databáze: Complementary Index