Autor: |
Cao, Chengrong, Tang, Wei, Perepezko, John H. |
Předmět: |
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Zdroj: |
Journal of Chemical Physics; 8/21/2022, Vol. 157 Issue 7, p1-8, 8p |
Abstrakt: |
The kinetics of the first order liquid–liquid transition (LLT) in a single-component liquid D-mannitol have been examined in detail by the high rate of flash differential scanning calorimetry measurements. By controlling the annealing temperature, the phase X formation from the supercooled liquid is distinguished by either a nucleation-growth or a spinodal-decomposition type of LLT. In the measured time–temperature-transformation curve the portion covering the nucleation-growth type of LLT can be well fitted with a classical nucleation theory analysis. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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