Rapid access to organic triflates based on flash generation of unstable sulfonium triflates in flow.

Autor: Takumi, Masahiro, Sakaue, Hodaka, Shibasaki, Daiki, Nagaki, Aiichiro
Předmět:
Zdroj: Chemical Communications; 8/4/2022, Vol. 58 Issue 60, p8344-8347, 4p
Abstrakt: Flash (extremely fast) electrochemical generation of unstable arylbis(arylthio)sulfonium triflates [ArS(ArSSAr)]+ [OTf] that are unsuitable for accumulation in batch processes was achieved within 10 s in a divided-type flow electrochemcial reactor, enabling one-flow access to vinyl triflates, short-lived oxocarbenium triflates and glycosyl triflates. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index