Asphaltenes as model compounds of the UIBs/AIBs detected in various astrophysical objects. Part 3: Petroleum asphaltenes high energy radiation processed.

Autor: García-Hernández, Domingo Aníbal, Manchado, Arturo, Cataldo, Franco
Předmět:
Zdroj: Fullerenes, Nanotubes & Carbon Nanostructures; 2022, Vol. 30 Issue 9, p923-935, 13p
Abstrakt: The asphaltenes isolated from a heavy petroleum fractions were subjected to radiation damage using either neutron bombardment (corpuscular radiation simulating cosmic rays) or γ-rays (high energy electromagnetic radiation). The purpose was to study how the radiation damage changes the spectral, thermal properties and other properties of the asphaltenes in a possible simulation of the destiny of these molecules exposed to the harsh circumstellar and interstellar medium. In fact, the asphaltenes were proposed as model molecules matching the MAONs model (mixed aromatic/aliphatic organic nanoparticles), the supposed carriers of the unidentified infrared bands known also as aromatic infrared bands or the unidentified infrared bands which represent a series of discrete infrared emission bands detected in numerous and different astrophysical environments. Thus, the pristine and radiation-damaged asphaltenes were studied with scanning electron microscopy, FTIR spectroscopy, electronic absorption spectroscopy, thermogravimetric analysis (TGA-DTG) and electron spin resonance. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index