Synergistic Dual Amine/Transition Metal Catalysis: Recent Advances.

Autor:	Venugopalan Nair, Vysakh, Arunprasath, Dhanarajan, Pandidurai, Solai, Sekar, Govindasamy
Předmět:	TRANSITION metals ORGANOCATALYSIS TRANSITION metal catalysts CATALYSIS BRONSTED acids LEWIS bases ACID catalysts
Zdroj:	European Journal of Organic Chemistry; 6/20/2022, Vol. 2022 Issue 23, p1-16, 16p
Abstrakt:	Dual Catalysis has enabled a plethora of novel unconventional transformations that would have been unattainable by either catalyst alone. The enormous potential of dual catalysis hinges on the synergistic activation of two substrates in discrete catalytic cycles without interfering with one another. The last decade had witnessed diverse dual‐catalyst systems focusing mainly on the combination of transition metal catalysis with either one of Lewis acid catalysis, photoredox catalysis, biocatalysis or organocatalysis (i. e., Lewis bases, Brønsted acids and NHC catalysts). In this setting, the scientific community has greatly embraced the integration of amine catalysts with transition metal catalysts. This Review comprehends the reported examples from the past decade on dual amine/transition metal catalysis and discuss the various activation modes for the functionalisation of carbonyl compounds. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.