Synthesis of δ-Valerolactone Using Stable Hydrogen Peroxide Derivatives.

Autor:	Solovyova, Ya. V., Puzyrev, I. S., Pervova, M. G., Kuznetsov, V. A., Vlasov, I. A., Artemiev, G. A., Pestov, A. V.
Předmět:	HYDROGEN peroxide BAEYER-Villiger rearrangement HYDROPEROXIDES TRIFLUOROACETIC acid MAGNESIUM OXIDIZING agents
Zdroj:	Russian Journal of Organic Chemistry; Apr2022, Vol. 58 Issue 4, p480-483, 4p
Abstrakt:	The efficiencies of hydrogen peroxide derivatives in the Baeyer–Villiger oxidation of cyclopen-tanone to δ-valerolactone have been compared. The oxidants used were hydrogen peroxide in acetic, formic, or trifluoroacetic acid, magnesium and sodium monoperoxyphthalates, cumene hydroperoxide, and tert-butyl hydroperoxide. The oxidation was carried out in water, aqueous methanol, and water–ethyl acetate. Sodium and magnesium monoperoxyphthalates turned out to provide high conversion and selectivity under mild conditions. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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