A Cyclopalladated BODIPY Construct as a Fluorescent Probe for Carbon Monoxide.

Autor:	Çevik Eren, Merve, Eren, Ahmet, Dartar, Suay, Buse Tütüncü, Büşra, Emrullahoğlu, Mustafa
Předmět:	CARBON monoxide FLUORESCENT probes STAINS & staining (Microscopy) PALLADIUM
Zdroj:	European Journal of Inorganic Chemistry; 5/17/2022, Vol. 2022 Issue 14, p1-5, 5p
Abstrakt:	By introducing a palladium ion into the backbone of BODIPY, we devised a cyclopalladated BODIPY construct that was almost non‐emissive in the absence of any analyte but became highly fluorescent upon interacting with carbon monoxide (CO) in solution and in living cells. A process of ortho‐carbonylation and depalladation mediated by the specific binding of CO to palladium, promoted the release of the heavy atom from the fluorophore and consequently generated a fluorescence signal with an exceptionally high (60‐fold) enhancement ratio. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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