| Autor: |
Miele, Margherita, Castoldi, Laura, Simeone, Xenia, Holzer, Wolfgang, Pace, Vittorio |
| Předmět: |
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| Zdroj: |
Chemical Communications; 5/11/2022, Vol. 58 Issue 38, p5761-5764, 4p |
| Abstrakt: |
The commercially available and experimentally convenient (bp 65 °C) difluoromethyltrimethylsilane (TMSCHF2) is proposed as a valuable difluoromethylating transfer reagent for delivering the CHF2 moiety to various heteroatom-based electrophiles. Upon activation with an alkoxide, a conceptually intuitive nucleophilic displacement directly furnishes in high yields the bench-stable analogues. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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