| Autor: |
Wang, Yu., Vakhrusheva, D. M., Krylova, I. V., Kozmenkova, A. Ya., Nikolaevskaya, E. N., Mankaev, B. N., Minyaev, M. E., Syroeshkin, M. A., Egorov, M. P., Jouikov, V. V. |
| Předmět: |
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| Zdroj: |
Russian Journal of Coordination Chemistry; Feb2022, Vol. 48 Issue 2, p69-74, 6p |
| Abstrakt: |
1,1'-Diphenyl-bis(silatrane) (I) was obtained by the reaction of tris(1,3-dihydroxypropan-2-yl)amine (L) with PhSi(OEt)3 in toluene. The molecular structure of complex I was established by X-ray diffraction (CIF file CCDC no. 2078347). Study of the redox properties of new bis(silatrane) I demonstrated that its radical ions generated by cyclic voltammetry are stable since the radical center located on the nitrogen atom is sterically protected within the bis(atrane) cage. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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