| Autor: |
Dodonov, Vladimir A., Kushnerova, Olga A., Rumyantsev, Roman V., Novikov, Alexander S., Osmanov, Vladimir K., Fedushkin, Igor L. |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 3/14/2022, Vol. 51 Issue 10, p4113-4121, 9p |
| Abstrakt: |
Heterocumulenes Se＝C＝NR (R = C6H4OMe-2, C6H4Me-2) undergo facile cycloaddition to [(H-dpp-bian)Na(Et2O)2] (1) (H-dpp-bian = N-protonated 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) resulting in cycloadducts [(H-dpp-bian)Na(SeCNR)(DME)] (2, 3), which are the first cycloadducts derived from a sodium metallacycle reported so far. A comparative reaction of [(dpp-bian)Mg(THF)3] (10) with Se＝C＝NR gives magnesium cycloadducts [(dpp-bian)Mg(SeCNR)(Solv)2] (11, 12), which undergo fast decomposition at room temperature. New compounds are characterized by NMR, EPR, and IR spectroscopy, and elemental and X-ray diffraction analysis. Their electronic structures and reaction pathways were probed using DFT calculations. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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