Phase transitions in Zr at sub-nanosecond time scales.

Autor: Grivickas, P., Austin, R. A., Armstrong, M. R., Radousky, H. B., Belof, J. L.
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Zdroj: Journal of Applied Physics; 2/28/2022, Vol. 131 Issue 8, p1-11, 11p
Abstrakt: Solid-solid phase transitions are investigated in Zr thin films using shock compression induced by a short laser pulse (<1 ns). Shock wave profiles are measured at free surfaces for films of different thicknesses (a few micrometers) using chirped-pulse line velocimetry with 10 ps time resolution. Experiments are performed at pressures up to ∼50 GPa, which is sufficient to reach the ω and β phases under equilibrium conditions. The shock wave structures are analyzed using a general Lagrangian analysis method, which allows for the calculation of stress–strain paths and assessments of phase transition behavior. In agreement with recent short laser pulse experiments using ultra-fast x-ray diffraction, we do not find any clear evidence of the α–ω transition, though this would be expected from the phase diagram. Instead, we infer a direct transformation to a metastable β-phase at lower shock pressures (<20 GPa) and equilibrium β at higher pressures. Through the velocimetry analysis, we find α–β transformation onset times of less than ∼100 ps and completion times of less than ∼200 ps. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index