Photochemical Sandmeyer‐type Halogenation of Arenediazonium Salts.

Autor:	Sivendran, Nardana, Belitz, Florian, Sowa Prendes, Daniel, Manu Martínez, Ángel, Schmid, Rochus, Gooßen, Lukas J.
Předmět:	HALOGENATION METAL catalysts DIAZONIUM compounds BROMINATION CHLORINATION CATALYSTS
Zdroj:	Chemistry - A European Journal; 2/16/2022, Vol. 28 Issue 9, p1-6, 6p
Abstrakt:	Trihalide salts were found to efficiently promote photochemical dediazotizing halogenations of diazonium salts. In contrast to classical Sandmeyer reactions, no metal catalysts are required to achieve high yields and outstanding selectivities for halogenation over competing hydridodediazotization. Convenient protocols are disclosed for synthetically meaningful brominations, iodinations, and chlorinations of diversely functionalized derivatives. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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