| Autor: |
Xiang, Danlei, Lin, Sheng-Chih, Deng, Jiao, Chen, Hao Ming, Liu, Chong |
| Předmět: |
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| Zdroj: |
Chemical Communications; 2/21/2022, Vol. 58 Issue 15, p2524-2527, 4p |
| Abstrakt: |
The roles of unforgiving H2SO4 solvent in CH4 activation with molecular catalysts have not been experimentally well-illustrated despite computational predictions. Here, we provide experimental evidence that metal-bound bisulfate ligand introduced by H2SO4 solvent is redox-active in vanadium-based electrocatalytic CH4 activation discovered recently. Replacing one of the two terminal bisulfate ligands with redox-inert dihydrogen phosphate in the pre-catalyst vanadium (V)-oxo dimer completely quenches its activity towards CH4, which may inspire environmentally benign catalysis with minimal use of H2SO4. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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