| Autor: |
Kirchhoff, Jan-Lukas, Koller, Stephan G., Louven, Kathrin, Strohmann, Carsten |
| Předmět: |
|
| Zdroj: |
Acta Crystallographica Section E: Crystallographic Communications; Jan2022, Vol. 78 Issue 2, p135-139, 11p |
| Abstrakt: |
The title molecular salt, C17H30NSi+·C2H5O4S-, belongs to the class of a-aminosilanes and was synthesized by the alkylation of 1-[(benzyldimethylsilyl)methyl]piperidine using diethyl sulfate. This achiral salt crystallizes in the chiral space group P21. One of the Si--C bonds in the cation is unusually long [1.9075 (12) Å], which correlates with the adjacent quaternary N+ atom and was verified by quantum chemical calculations. In the crystal, the components are linked by weak C--H...O hydrogen bonds: a Hirshfeld surface analysis was performed to further investigate these intermolecular interactions and their effects on the crystal packing. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
