Acetylene and Ethylene: Universal C2 Molecular Units in Cycloaddition Reactions.

Autor: Ledovskaya, Maria S., Voronin, Vladimir V., Rodygin, Konstantin S., Ananikov, Valentine P.
Předmět:
Zdroj: Synthesis; Feb2022, Vol. 54 Issue 4, p999-1042, 44p
Abstrakt: Acetylene and ethylene are the smallest molecules that contain an unsaturated carbon–carbon bond and can be efficiently utilized in a large variety of cycloaddition reactions. In this review, we summarize the application of these C2 molecular units in cycloaddition chemistry and highlight their amazing synthetic opportunities. 1 Introduction 2 Fundamental Features and Differences of Cycloaddition Reactions Involving Acetylene and Ethylene 3 (2+1) Cycloaddition 4 [2+2] Cycloaddition 5 (3+2) Cycloaddition 6 [4+2] Cycloaddition 7 (2+2+1) Cycloaddition 8 [2+2+2] Cycloaddition 9 The Use of Acetylene and Ethylene Cycloaddition for Deuterium and13 C Labeling 10 Conclusions [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index