Immobilization of Technetium into a Sodium-Aluminum-Iron Phosphate Glass: Degree of Oxidation of Technetium and Iron, Hydrothermal Stability of the Glass.

Autor: Danilov, S. S., Frolova, A. V., Teterin, A. Yu., Maslakov, K. I., Teterin, Yu. A., Kulikova, S. A., Vinokurov, S. E.
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Zdroj: Radiochemistry; 2021, Vol. 63 Issue 6, p843-850, 8p
Abstrakt: Glass samples containing 3 wt % of KTcO4 have been synthesized in the system, mol %: 40Na2O–10Al2O3–10Fe2O–40P2O5. The glass samples have been studied by X-ray photoelectron spectroscopy. It was found that the degree of technetium oxidation is Tc(IV), which differs from the behavior of rhenium under similar conditions: about 83% of Fe is present as Fe(III), and the rest, as Fe(II). A high stability of the lass against leaching at 90°C was demonstrated in the half-dynamic test (State Standard R 52126–2003): the rate of Tc leaching from the glass is about 3 × 10–6 g/(cm2 day). [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index