Double isomerization/cycloisomerization/aromatization of 1-(allyloxy)-2-(cyclopropylmethyl)benzenes to give 2-ethyl-3-isopropylbenzofurans using a multitasking single rhodium catalyst.

Autor: Sato, Yuta, Matsuzaki, Tsuyoshi, Takehara, Tsunayoshi, Sako, Makoto, Suzuki, Takeyuki, Arisawa, Mitsuhiro
Předmět:
Zdroj: Chemical Communications; 1/11/2022, Vol. 58 Issue 3, p415-418, 4p
Abstrakt: Multitasking single-catalyst systems that allow multiple chemical transformations within a single reaction vessel are important for the development of eco-compatible chemistry. Here, we have developed a rhodium-catalyzed system that transforms 1-(allyloxy)-2-(cyclopropylmethyl)benzene derivatives to 2-ethyl-3-isopropylbenzofurans via double isomerization/cycloisomerization/aromatization. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index