Photoinduced Atom Transfer Radical Addition/Cyclization Reaction between Alkynes or Alkenes with Unsaturated α-Halogenated Carbonyls.

Autor:	Matsuo, Kazuki, Yoshitake, Tadashi, Yamaguchi, Eiji, Itoh, Akichika
Předmět:	CYCLOPENTANE CARBON-carbon bonds UNSATURATED compounds ALKYNES ALKENES ACID derivatives RING formation (Chemistry)
Zdroj:	Molecules; Nov2021, Vol. 26 Issue 22, p6781-6781, 1p
Abstrakt:	We have developed a photochemical ATRA/ATRC reaction that is mediated by halogen bonding interactions. This reaction is caused by the reaction of malonic acid ester derivatives containing bromine or iodine with unsaturated compounds such as alkenes and alkynes in the presence of diisopropylethylamine under visible light irradiation. As a result of various control experiments, it was found that the formation of complexes between amines and halogens by halogen-bonding interaction occurs in the reaction system, followed by the cleavage of the carbon–halogen bonds by visible light, resulting in the formation of carbon radicals. In this reaction, a variety of substrates can be used, and the products, cyclopentenes and cyclopentanes, were obtained by intermolecular addition and intramolecular cyclization. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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