Nucleophilic borylation of fluorobenzenes with reduced arylboranes.

Autor: Budy, Hendrik, Prey, Sven E., Buch, Christoph D., Bolte, Michael, Lerner, Hans-Wolfram, Wagner, Matthias
Předmět:
Zdroj: Chemical Communications; 1/7/2022, Vol. 58 Issue 2, p254-257, 4p
Abstrakt: Two challenging but rewarding topics in chemical synthesis are C–F-bond activation and the development of B-centered nucleophiles. We have now tackled both subjects simultaneously by forming aryl–B bonds via SNAr-type reactions on fluorobenzenes under mild conditions using Na2[FluB=BFlu], Li2[HBFlu], and Li2[Me2DBA] (BFlu = 9-borafluorenyl, Me2DBA = 9,10-dimethyl-9,10-dihydro-9,10-diboraanthracene). [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index