Self‐photocatalyzed Homolytic Dehalogenative Alkylation/Cyclization of Unactivated Alkenes Based on the Quinazolinone Skeleton via Energy Transfer.

Autor: Sun, Bin, Tang, Xiaoli, Shi, Rongcheng, Yan, Zhiyang, Li, Bingqian, Tang, Chen, Jin, Can, Wu, Chunlei L., Shen, Runpu P.
Předmět:
Zdroj: Asian Journal of Organic Chemistry; Dec2021, Vol. 10 Issue 12, p3390-3395, 6p
Abstrakt: A mild, external photocatalyst‐ and additive‐free protocol for photo‐induced alkylation/cyclization of unactivated alkenes with halides has been developed. This strategy showed excellent regioselectivity and simple operation to synthesize alkyl‐substituted quinazolinones with a broad substrate scope. More importantly, chlorinated alkanes were also compatible with this transformation. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index