| Abstrakt: |
A new highly aromatic hardener, phenylated phenylenediamine (PDA), was synthesized utilizing a Diels‐Alder reaction to afford a mixture of para and meta conformations. This new hardener was cured with bisphenol A diglycidyl ether (BADGE). To investigate the conformational mixture, pure 1,4‐benzenediamine and 1,3‐benzenediamine were cured with BADGE. DSC was employed to observe cure curves affording the onset (73, 74, and 146°C for 1,4‐benzenediamine, 1,3‐benzenediamaine, and phenylated phenylenediamine, respectively), peak (128, 151, and 206°C, respectively), and enthalpy change (385, 526, and 238 J/g, respectively), as well as the glass transition temperature (103, 151, and 212°C, respectively). ATR‐FTIR spectroscopy provided information on the structures of the cured network samples, including loss of oxirane and primary amine vibrations after curing. TGA and DMA were used to determine thermal stability (Td,N2 = 332, 367, and 380°C, respectively) and thermal mechanical properties including storage (E′ = 200, 150, and 350 MPa, respectively), loss modulus (E″ = 10, 10, and 40 MPa, respectively), and tan delta (102, 180, and 209°C, respectively). [ABSTRACT FROM AUTHOR] |
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