| Autor: |
Söllinger, Daniela, Berger, Thomas, Redhammer, Günther J., Schoiber, Jürgen, Pokrant, Simone |
| Předmět: |
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| Zdroj: |
ChemElectroChem; 11/12/2021, Vol. 8 Issue 22, p4223-4232, 10p |
| Abstrakt: |
Due to a growing demand for sustainable electrical energy storage alternatives to Li‐ion batteries (LIBs), Na‐ion batteries (SIBs) are of great interest because of the abundance of Na+. By modifying layered H2V3O8 by preintercalation and composite formation, improved electrochemical properties were obtained in LIBs. In analogy, a scalable soft chemistry synthesis is developed, to chemically presodiate H2V3O8 for the first time, in addition to a composite formation reaction with reduced graphene oxide (rGO). Crystal structure and morphology of all compounds are determined and their electrochemical properties as cathode are evaluated with respect to both Na+ and Li+ intercalation. The combination of preintercalation and composite formation leads to excellent initial capacities of 96 mAh ⋅ g−1 for SIBs and 371 mAh ⋅ g−1 for LIBs (58 % and 48 % higher than unmodified H2V3O8) at a practical current density of 100 mA ⋅ g−1, demonstrating that H2V3O8 is a promising cathode material for SIBs and LIBs. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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