| Autor: |
Kitagawa, Yuichi, Ferreira da Rosa, Pedro Paulo, Hasegawa, Yasuchika |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 11/14/2021, Vol. 50 Issue 42, p14978-14984, 7p |
| Abstrakt: |
Transition metal complexes provide photofunctional properties through the charge transfer excited states of their metal ion and organic ligand components. Recently, there are increasing reports on the charge transfer excited states of the ligand (π)- and 4f-orbitals of lanthanide complexes, where the latter are shielded by filled 5s2 and 5p6 orbitals. This area of research is relatively unestablished; thus, the study of photo-excited organic–lanthanide charge transfer would lead to the construction of next-generation photofunctional metal complexes. In this review, we summarize the latest research progress in photofunctional materials using the charge transfer excited states of lanthanide complexes, and discuss the photophysical/theoretical analyses of these charge transfer excited states. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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