Time Resolved Ligand Loss: Flash Photolysis and UV–Vis Spectroscopic Studies of cis-[Ru(bpy)2(py)2]2+ Complex.

Autor:	Rahman, Mohammad Aminur
Zdroj:	Russian Journal of Physical Chemistry; Nov2021, Vol. 95 Issue 11, p2341-2347, 7p
Abstrakt:	A preliminary study on photoinduced ligand loss from [Ru(bpy)2(py)2]2+ has been made. The photolysis of cis-[Ru(bpy)2(py)2]2+ in the presence of trifluoroacetic acid, using broad band, white light excitation, leads to a shift in λmax from 458 nm to 472 nm, consistent with a substitution reaction of the pyridine by THF. A flash photolysis study was also performed to investigate the excited state changes of [Ru(bpy)2(py)2]2+ in THF. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Full text from SpringerLink