Amine-Iodine Adducts as Simple but Effective Catalysts for the Synthesis of Organic Carbonates from Epoxides and CO2.

Autor: Chowdhury, Biswajit, Zvinchuk, Anastasia A., Aysin, Rinat R., Khakina, Ekaterina A., Cherkasova, Polina V., Lyubimov, Sergey E.
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Zdroj: Catalysis Surveys from Asia; Dec2021, Vol. 25 Issue 4, p419-423, 5p
Abstrakt: New catalysts prepared by simple mixing of molecular iodine and inexpensive monodonor amines can efficiently catalyze the coupling of CO2 with different epoxides at moderate temperatures (60–90 °C), pressures (10–56 atm) and low (0.25–0.5 mol %) catalytic loading. The molecular systems can be considered as the simplest and most inexpensive catalyst for the reactions. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index