| Autor: |
van Leusen, Jan, Speldrich, Manfred, Kögerler, Paul |
| Zdroj: |
Topics in Organometallic Chemistry; 2018, Vol. 64, p391-410, 20p |
| Abstrakt: |
The magnetochemical interpretation of actinide ions in ligand environments represents a complex challenge, since the approximations and simplifications that are commonly employed in transition metal and lanthanide coordination compounds cannot be applied in the case of 5fN systems. We herein aim to deconvolute the various contributions to the magnetic characteristics of such systems, and we demonstrate how to construct appropriate microscopic model Hamiltonians. The approach to account for all relevant intrinsic effects is finally showcased by a number of examples. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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