Selective replacement of organosilicon units in the cluster [(PhSi)4S6] with coinage metal complex fragments.

Autor:	Nier, Simon, Ringelband, Sven, Dehnen, Stefanie
Předmět:	METAL complexes SILICON compounds COPPER clusters COINAGE COPPER compounds COPPER SILVER sulfide
Zdroj:	Chemical Communications; 10/11/2021, Vol. 57 Issue 79, p10254-10257, 4p
Abstrakt:	Adamantane-type organo-group 14 chalcogenide clusters were shown to possess extreme non-linear optical properties. Reactivity studies of corresponding organosilicon sulfide clusters towards copper and silver complexes indicate a replacement of exactly one of the organosilicon groups with a metal complex fragment to form [(Et3PAg)3(PhSi)3S6] (1) and [Na2(thf)2.33][(Me3PCu)(PhSi)3S6] (2)—in striking contrast to reactions of organotin chalcogenide clusters, which are more significantly and less systematically re-organized. The silicon compounds are thus more suited for controlled modifications of their geometric and electronic structures. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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