Synthesis and Chemoresistive Gas-Sensing Properties of Highly Dispersed Titanium-Doped Nb2O5.

Autor: Mokrushin, A. S., Simonenko, N. P., Simonenko, T. L., Simonenko, E. P., Sevast'yanov, V. G., Kuznetsov, N. T.
Zdroj: Russian Journal of Inorganic Chemistry; Sep2021, Vol. 66 Issue 9, p1425-1433, 9p
Abstrakt: Nb2O5–TiO2 nanomaterials containing 0.5 and 10 mol % TiO2 have been synthesized by the programmed deposition method. The products have been characterized by modern physicochemical methods The Nb2O5–TiO2 nanomaterials have a crystal structure of orthorhombic Nb2O5 (T-phase). Individual niobium oxide is composed of nanoparticles with an average size of 15 ± 3 nm; increasing the TiO2 content entails microstructural changes. For the Nb2O5–TiO2 coatings, a set of chemoresistive gas-sensing properties has been studied. Of all the analyzed gases, the highest sensitivity was recorded for oxygen and hydrogen sulfide. It has been shown that the sample with 5% TiO2 is most sensitive to О2 and H2S, which is explained by the formation of additional oxygen vacancies. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index