Relaxor ferroelectric-like behavior in 10PbTiO3–10Fe2O3–30V2O5–50B2O3 glass for energy storage applications.

Autor: EI-Desoky, M. M., Wally, N. K., Ali, A. M., Harby, Amany E., Hannora, Ahmed E.
Předmět:
Zdroj: Journal of Materials Science: Materials in Electronics; Sep2021, Vol. 32 Issue 17, p22408-22416, 9p
Abstrakt: Recently, demand increased for dielectric materials used in energy storage devices at high voltage applications. Appearance of polar clusters in glass matrix could promote its use in energy storage applications. Conventional quenched glass sample of composition 10PbTiO3–10Fe2O3–30V2O5–50B2O3 were successfully developed. The glassy nature was confirmed by XRD and DSC measurements. Boson peak observed at low frequency from the Raman spectra confirms polar cluster formation. Dielectric properties of prepared glass were investigated in a wide range of frequency and temperature. Broad and diffuse peak of dielectric permittivity shifted to the higher temperatures, denoting the typical relaxor ferroelectrics like behavior. Sample shows energy storage density of about 164.7 mJ/cm3 at room temperature. Quenched glass sample shows typical anti-ferromagnetic behavior. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index