Enhanced Thermal Stability and Flame Retardancy of Poly(Vinyl Chloride) Based Composites by Magnesium Borate Hydrate-Mechanically Activated Lignin.

Autor: Zhang, Wuxiang, Wu, Haoran, Zhou, Nan, Cai, Xiunan, Zhang, Yanjuan, Hu, Huayu, Feng, Zhenfei, Huang, Zuqiang, Liang, Jing
Předmět:
Zdroj: Journal of Inorganic & Organometallic Polymers & Materials; Sep2021, Vol. 31 Issue 9, p3842-3856, 15p
Abstrakt: To improve the thermal stability and flame retardancy of poly(vinyl chloride) (PVC) based composites, magnesium borate hydrate-mechanically activated lignin (MBH-MAL) complex was in-situ synthesized by hydrothermal method for using as a novel additive. In addition, MBH-lignin (MBH-L) complex, MAL, MBH, and common mixing of MBH and MAL (MBH+MAL) were also prepared for comparative investigation. MBH-MAL showed synergistic improving effect on PVC as MBH-MAL/PVC composite exhibited excellent thermal stability and flame retardancy. The static thermal stability time was 871 s and limit oxygen index was 32.54%, indicating that MBH-MAL effectively inhibited the generation of HCl from thermal decomposition of PVC and prevented the combustion of PVC based composites in air. MBH-MAL/PVC composite still exhibited outstanding tensile and flexural properties. Moreover, the enhancing mechanism of MBH-MAL on the thermal stability and flame retardancy of PVC based composites was proposed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index