| Autor: |
Hitoshio, Kenshiro, Yamagishi, Hiroki, Shimokawa, Jun, Yorimitsu, Hideki |
| Předmět: |
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| Zdroj: |
Chemical Communications; 7/18/2021, Vol. 57 Issue 56, p6867-6870, 4p |
| Abstrakt: |
Structurally diverse aryl chlorides were silylated with sodium silylsilanolate reagents in the presence of a Ni(cod)2 catalyst complexed with a phosphine ligand; PMe2Ph for electron-rich substrates, and PCy2Ph for electron-deficient ones. The mild reaction conditions allowed the silylation of various aryl chlorides including functionalised drug molecules. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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