Alcohols, Ethers, and Esters with Peroxy Groups Prepared from 2-tert-Butylperoxy-2-methylpentan-4-one.

Autor: Yuvchenko, A. P., Dikusar, E. A., Zvereva, T. D., Murashko, V. L.
Předmět:
Zdroj: Russian Journal of Organic Chemistry; Feb2003, Vol. 39 Issue 2, p164-169, 6p
Abstrakt: 2-tert-Butylperoxy-2-methylpentan-4-one reacts with butyllithium providing saturated tertiary peroxyalcohol, with 1-lithioalkynes, among them lithiooxy- and peroxy-containing, gives rise to the corresponding tertiary acetylene mono- and diperoxyalcohols and diols. The thermal stability of peroxides obtained was evaluated by derivatography. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index