Charge-Transfer Complexes between Substituted Pyridine N-Oxides and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone.

Autor:	Shaforost, K. V., Semenov, S. G., Sverdlova, O. V., Rodina, L. L.
Předmět:	SPECTROPHOTOMETRY ANALYTICAL chemistry PYRIDINE HETEROCYCLIC compounds NITROGEN oxides CHARGE transfer
Zdroj:	Russian Journal of General Chemistry; Mar2003, Vol. 73 Issue 3, p450-454, 5p
Abstrakt:	Spectrophotometry was used to study charge-transfer complexes between substituted pyridine N-oxides and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone. Vertical ionization potentials of pyridine N-oxides in the gas phase and in solution were calculated by the CNDO/S3' method. The calculated ionization potentials in chloroform nicely correlate with the experimental charge-transfer wavelengths of the complexes. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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