Sorption–Spectrophotometric and Test Determination of Zinc(II) as the Mixed-Ligand Complex of 1,10-Phenanthroline and Bromophenol Blue.

Autor: Zaporozhets, O. A., Ivan'ko, L. S., Bykova, L. V., Mostovaya, N. A.
Předmět:
Zdroj: Journal of Analytical Chemistry; Jan2004, Vol. 59 Issue 1, p23-27, 5p
Abstrakt: The interaction of Zn(II), Cd(II), and Pb(II) with 1,10-phenanthroline noncovalently immobilized on silica in the presence of Bromophenol Blue was studied. The optimum conditions of the reaction and the composition of mixed-ligand complexes that are formed at the surface were found, and a scheme was proposed for the interaction at the interface. A sorption–spectrophotometric procedure and a test scale were developed for the determination of zinc with detection limits of 0.011 and 0.018 mg/L, respectively. The procedure was used for the determination of labile zinc species in soil. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index