Circular Dichroism Spectra of 5- and 7-Bromo-6-ketosteroids.

Autor: Kovganko, N. V., Sokolov, S. N., Survilo, V. L., Garbuz, N. I., Yankovskaya, G. S.
Předmět:
Zdroj: Chemistry of Natural Compounds; Jan/Feb2004, Vol. 40 Issue 1, p45-49, 5p
Abstrakt: Circular dichro ism spectra of 5α- and 7α-bro rno-6-ketoste roids ofthe cho lestane and stigmastan e series were studied. A negative Cotton effect corresponding to the n-π* -transition of the ketone was observed in the CD spectra of 5α-bromo-6-ketosteroids at 300 nm. The analogous Cotton effect was positive in CD spectra of 7α-bromo-6-ketosteroids. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index