| Autor: |
Lomnytska, Ya. F., Guérin, R., Oryshchyn, S. V., Kuz'ma, Yu. B., Babizhetskyy, V. S. |
| Předmět: |
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| Zdroj: |
Inorganic Materials; Jul2004, Vol. 40 Issue 7, p700-706, 7p |
| Abstrakt: |
A new ternary compound of composition (V,Mo)84P49 (V3.2Mo8.8P7) is synthesized, and its structure is determined by single-crystal x-ray diffraction: a new structure type, sp. gr. P&6macr;, a = 2.52015(3) nm, c = 0.3 30070(5) nm; RF = 0.054, Rw = 0.05 8 for 1894 independent reflections with Fhkl > 4.0σFhkl. V3.2Mo3.8P7 is shown to contain mixed-occupancy (V, Mo) sites. The (V,Mo)84P49 and (Ti,Mo)36P21 structure types belong to a homologous series containing Cr12P7 as the n = 1 member. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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