Crystal Structures of Zr2Mn12P7 and (Mo,Mn)12P7.

Autor: Oryshchyn, S.V., Zhak, O.V., S. Deputier, Le Sénéchal, C., Guérin, R.
Předmět:
Zdroj: Inorganic Materials; Jun2004, Vol. 40 Issue 6, p616-622, 7p
Abstrakt: Single-crystal x-ray diffraction was used to determine the crystal structures of the ternary phosphides Zr2Mn12P7 (sp. gr. P63/m, a new structure type derived from the Zr2Fe12P7 type, a = 0.9348(2) nm, c = 0.35755(5) nm, R = 0.039, Rw = 0.041) and (Mo,Mn)12P7 (sp. gr. P&6macr;, a new structure type derived from the Cr12P7 type, a= 0.393242(4) nm, c = 0.33807(1) nm, R = 0.048, Rw = 0.049). [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index