| Autor: |
Lobachev, V. L., Kluger, S. L., Zimtseva, G. P., Geletii, Yu. V., Rudakov, E. S. |
| Předmět: |
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| Zdroj: |
Theoretical & Experimental Chemistry; Jan2003, Vol. 39 Issue 1, p41-47, 7p |
| Abstrakt: |
The kinetic features of the oxidation of alkenes by peroxynitrous acid (HOONO) generated in the H2O2-HNO2/acetate buffer (pH 4.27) system, are quantitatively explained assuming simultaneous reactions in the gas and liquid phases. A remarkable similarity is found for the substrate selectivities of the gas-phase reactions of alkenes as well as of alkanes and arenes with HOONO and with OH radicals. The reaction mechanism is discussed. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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