Milled Dry Ice as a C1 Source for the Carboxylation of Aryl Halides.

Autor: O'Brien, Connor J., Nicewicz, David A.
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Zdroj: Synlett; 2021, Vol. 32 Issue 8, p814-816, 3p
Abstrakt: The use of carbon dioxide as a C1 chemical feedstock remains an active field of research. Here we showcase the use of milled dry ice as a method to promote the availability of CO2 in a reaction solution, permitting practical synthesis of arylcarboxylic acids. Notably, the use of milled dry ice produces marked increases in yields relative to those obtained with gaseous CO2 , as previously reported in the literature. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index