Alkali-Activated Binders Using Bottom Ash from Waste-to-Energy Plants and Aluminium Recycling Waste.

Autor: Maldonado-Alameda, Alex, Mañosa, Jofre, Giro-Paloma, Jessica, Formosa, Joan, Chimenos, Josep Maria, Crea, Fortunato, Candamano, Sebastiano
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Zdroj: Applied Sciences (2076-3417); May2021, Vol. 11 Issue 9, p3840, 15p
Abstrakt: Alkali-activated binders (AABs) stand out as a promising alternative to replace ordinary Portland cement (OPC) due to the possibility of using by-products and wastes in their manufacturing. This paper assessed the potential of weathered bottom ash (WBA) from waste-to-energy plants and PAVAL® (PV), a secondary aluminium recycling process by-product, as precursors of AABs. WBA and PV were mixed at weight ratios of 98/2, 95/5, and 90/10. A mixture of waterglass (WG) and NaOH at different concentrations (4 and 6 M) was used as the alkaline activator solution. The effects of increasing NaOH concentration and PV content were evaluated. Alkali-activated WBA/PV (AA-WBA/PV) binders were obtained. Selective chemical extractions and physicochemical characterization revealed the formation of C-S-H, C-A-S-H, and (N,C)-A-S-H gels. Increasing the NaOH concentration and PV content increased porosity and reduced compressive strength (25.63 to 12.07 MPa). The leaching potential of As and Sb from AA-WBA/PV exceeded the threshold for acceptance in landfills for non-hazardous waste. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index