| Autor: |
Abd Allah, Omyma A. A., Kaur, Manpreet, Akkurt, Mehmet, Mohamed, Shaaban K., Jasinski, Jerry P., Elgarhy, Sahar M. I. |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Crystallographic Communications; Mar2021, Vol. 77 Issue 3, p247-250, 11p |
| Abstrakt: |
In the title compound, C27H33NO5, a 3,3,6,6-tetramethyltetrahydroacridine-1,8-dione ring system carries an ethyl acetate substituent on the acridine N atom and an o-hydroxyphenyl ring on the central methine C atom of the dihydropyridine ring. The benzene ring is inclined to the acridine ring system at an angle of 80.45 (7)° and this conformation is stabilized by an intramolecular O--H
O hydrogen bond between the hydroxy substituent on the benzene ring and one of the carbonyl groups of the acridinedione unit. The ester C=O oxygen atom is disordered over major and minor orientations in a 0.777 (9):0.223 (9) ratio and the terminal--CH3 unit of the ethyl side chain is disordered over two sets of sites in a 0.725 (5): 0.275 (5) ratio. In the crystal, C--H
O hydrogen bonds combine to link the molecules into a three-dimensional network. van der Waals H
H contacts contribute the most to the Hirshfeld surface (66.9%) followed by O
H/H
O (22.1%) contacts associated with weak hydrogen bonds. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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